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In the upper-right corner of any page, click your profile photo, then click Settings.
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In the "Code, planning, and automation" section of the sidebar, click Repositories.
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Next to the repository you want to leave, click Leave.
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Read the warning carefully, then click "I understand, leave this repository."
Removing yourself from a collaborator's repository
If you no longer want to be a collaborator on someone else's repository, you can remove yourself.